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CATALYSIS AND SYNTHETIC ORGANIC CHEMISTRY
PUBLICATIONS

     

28.


Synthesis of Glycoporphyrins Using Trichloroacetimidates as Glycosyl Donors
D. Aicher, A. Wiehe, C. B. W. Stark
Synlett 2010, 395 - 398. DOI: 10.1055/s-0029-1219355

 

27.



A Double Donor-Activated Ruthenium(VII) Catalyst: Synthesis of Enantiomerically Pure THF-Diols
H. Cheng, C. B. W. Stark
Angew. Chem. 2010, 122, 1632 - 1635; Angew. Chem. Int. Ed. 2010, 49, 1587 - 1590. DOI: 10.1002/anie.200903090
Highlighted in Synfacts 2010, 0565. DOI: 10.1055/s-0029-1219639

 

26.


Vanadium diboride catalyzed oxidation of cyclooctene by molecular oxygen: Kinetic study
Y. B. Trach, L. V. Bulgakova, O. I. Makota, W. Y. Suprun, B. Schulze, C. B. W. Stark
J. Mol. Catal. A: Chem. 2009, 302, 124 - 128. DOI:10.1016/j.molcata.2008.12.008

 

25.


A new catalytic oxidation reaction to furnish lactones
S. Roth, C. B. W. Stark
Chem. Commun. 2008, 6411 - 6413. DOI: 10.1039/b815135k

 

24.



A straightforward synthesis of alkenyl nonaflates from carbonyl compounds using nonafluorobutane-1-sulfonyl fluoride in combination with phosphazene bases
M. A. K. Vogel, C. B. W. Stark, I. M. Lyapkalo
Synlett 2007, 2907-2911. DOI: 10.1055/s-2007-991084

 

23.


Multigram synthesis of diastereomerically pure tetrahydrofuran-diols
S. Göhler, S. Roth, H. Cheng, H. Göksel, A. Rupp, L. O. Haustedt, C. B. W. Stark
Synthesis 2007, 2751-2754. DOI: 10.1055/s-2007-983797

 

22.



An expedient variant of heck reaction of alkenyl nonaflates: Homogeneous ligand-free palladium catalysis at room temperature
M. A. K. Vogel, C. B. W. Stark, I. M. Lyapkalo
Adv. Syn. Catal. 2007, 349, 1019-1024. DOI: 10.1002/adsc.200600388

 

21.


Catalytic Diastereo- and Positionselective Oxidative Mono-Cyclization of 1,5,9-Trienes and Polyenes
S. Göhler, C. B. W. Stark
Org. Biomol. Chem. 2007, 5, 1605-1614. DOI: 10.1039/b702877f

 

20.


Efficient Oxidative Cyclization of 1,6-Dienes: A Highly Diastereoselective Entry to Substituted Tetrahydropyrans
S. Roth, C. B. W. Stark
Angew. Chem. 2006, 118, 6364-6367; Angew. Chem. Int. Ed. 2006, 45, 6218-6221. DOI: 10.1002/anie.200504572

 

19.



Total Synthesis of cis-Solamin: Exploiting the RuO4-Catalyzed Oxidative Cyclization of Dienes
H. Göksel, C. B. W. Stark
Org. Lett. 2006, 8, 3433-3436. DOI: 10.1021/ol060520k
Highlighted in Synfacts 2007, 0012.

 

18.



Evidence for the Role of the monB Genes in Polyether Ring Formation during Monensin Biosynthesis
Gallimore, A. R.; Stark, C. B. W.; Bhatt, A.; Harvey, B. M.; Demydchuk, Y.; Bolanos-Garcia, V.; Fowler, D. J.; Staunton, J.; Leadlay, P. F.; Spencer, J. B.
Chem. Biol. 2006, 13, 453-460.

 

17.



Accumulation of an E,E,E-Triene by a Polyether-producing Polyketide Synthase When Oxidative Cyclization is Wholly Blocked
Bhatt, A.; Stark, C. B. W.; Harvey, B. M.; Gallimore, A. R.; Spencer, J. B.; Staunton, J.; Leadlay, P. F.
Angew. Chem. 2005, 117, 7237-7240; Angew. Chem. Int. Ed. 2005, 44, 7075-7078.

 

16.


A Highly Efficient Procedure for Ruthenium Tetroxide Catalyzed Oxidative Cyclizations of 1,5-Dienes
S. Roth, S. Göhler, H. Cheng, C. B. W. Stark
Eur. J. Org. Chem. 2005, 4109-4118.

 

15.


Studies on the Asymmetric Dihydroxylation of Advanced Bryostatin C-Ring Segments
Seidel, M. C.; Smits, R.; Stark, C. B. W.; Frackenpohl, J.; Gaertzen, O.; Hoffmann, H. M. R.
Synthesis 2004, 1391-1398.

 

14.


Evidence for gas-phase redox chemistry inducing novel fragmentation in a complex natural product
Lopes, N. P ; Stark, C. B. W.; Staunton, J.; Gates, P. J.
Org. Biomol. Chem. 2004, 2, 358-363.

 

13.


The Effect of Ruthenium(III) Chloride on the Formation of Protonated Parent Ions in Electrospray Mass Spectrometry
Stark, C. B. W.; Lopes, N. P.; Fonseca, T.; Gates, P. J.
J. Chem. Soc., Chem. Commun. 2003, 2732-2733.

 

12.



Sodium Monensin Dihydrate
Almeida Paz, F. A.; Gates, P. G.; Fowler, S.; Gallimore, A.; Harvey, B.; Lopes, N. P.; Stark, C. B. W.; Staunton, J.; Klinowski, J.; Spencer, J. B.
Acta Cryst. 2003, E59, m1050-m1052.

 

11.



Intermediates Released from a Polyether-producing Polyketide Synthase Provide Insight into the Mechanism of Oxidative Cyclisation
Hughes-Thomas, Z. A.; Stark, C. B. W.; Böhm, I.; Staunton, J.; Leadlay, P. F.
Angew. Chem. 2003, 115, 4613-4616; Angew. Chem., Int. Ed. 2003, 42, 4475-4478.

 

10.




Analysis of the Biosynthetic Gene Cluster for the Polyether Antibiotic Monensin in Streptomyces cinnamonensis and Evidence for the Role of monB and monC Genes in Oxidative Cyclization
Oliynyk, M.; Stark, C. B. W.; Bhatt, A.; Jones, M. A.; Hughes-Thomas, Z. A.; Wilkinson, C.; Oliynyk, Z.; Demydchuk, Y.; Staunton, J.; Leadlay, P. F.
Mol. Microbiol. 2003, 49, 1179-1190.

 

9.


Sesquiterpene Lactones from Lychnophora ericoides
Sakamoto, H. T.; Flausino, D.; Castellano, E. E.; Stark, C. B. W.; Gates, P. J.; Lopes, N. P.
J. Nat. Prod. 2003, 66, 693-695.

 

8.


Fragmentation Studies on Monensin A by sequential Electrospray Mass Spectrometry
Lopes, N. P.; Stark, C. B. W.; Gates, P. J.; Staunton, J.
Analyst 2002, 127, 503-506.

 

7.


Fragmentation Studies on Monensin A and B by Accurate Mass Electrospray Tandem Mass Spectrometry
Lopes, N. P.; Stark, C. B. W.; Hong, H.; Gates, P. J.; Staunton, J.
Rapid Commun. Mass Spectrom. 2002, 16, 414-420.

 

6.



Engineering of Complex Polyketide Biosynthesis – Insights from Sequencing the Monensin Biosynthetic Gene Cluster
Leadlay, P. F.; Staunton, J.; Oliynyk, M.; Bisang, C.; Cortés, J.; Frost, E.; Hughes-Thomas, Z. A.; Jones, M. A.; Kendrew, S. G.; Lester, J. B.; Long, P. F.; McArthur, H. A. I.; McCormick, E. L.; Oliynyk, Z.; Stark, C. B. W.; Wilkinson, C. J.
J. Industrial Microbiol. Biotechnol. 2001, 27, 360-367.

 

5.



A Study of the Effect of pH, Solvent System, Cone Potential and the Addition of Crown Ethers on the Formation of the Monensin Protonated Parent Ion in Electrospray Mass Spectrometry
Lopes, N. P.; Stark, C. B. W.; Gates, P. J.; Hong, H.; Staunton, J.
Analyst 2001, 126, 1630-1632.

 

4.



The Total Synthesis of C-Glycosides with Completely Resolved Seven-Carbon Backbone Polyol Stereochemistry. Stereochemical Correlations and Access to L-Configured and Other Rare Carbohydrates
Hoffmann, H. M. R.; Dunkel, R.; Mentzel, M.; Reuter, H.; Stark, C. B. W.
Chem. Eur. J. 2001, 7, 4771-4789.

 

3.



High Regio-, Chemo- and Stereoselectivity via Low Temperature [4+3] Cycloadditions. Convergent Synthesis of Multifunctionalized Vinylmetals (M = Si, Sn) and S-Vinyl Benzenecarbothiolates
Beck, H.; Stark, C. B. W.; Hoffmann, H. M. R.
Org. Lett. 2000, 2, 883-886.

 

2.



Chiral Allyl Cations Are Captured by Furan with 100% Stereoselectivity. Synthesis of Enantiopure 2-Alkoxy-8-oxabicyclo[3.2.1]oct-6-en-3-ones by Low Temperature [4+3] Cycloaddition
Stark, C. B. W.; Pierau, S.; Wartchow, R.; Hoffmann, H. M. R.
Chem. Eur. J. 2000, 6, 684-691.

 

1.



Chiral Allyl Cations in Cycloadditions to Furan: Synthesis of 2-(1`-Phenylethoxy)-8-oxabicyclo[3.2.1]oct-6-en-3-one in High Enantiomeric Purity
Stark, C. B. W.; Eggert, U.; Hoffmann, H. M. R.
Angew. Chem. 1998, 110, 1337-1338; Angew. Chem., Int. Ed. 1998, 37, 1266-1267.